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Although it is impossible to predict when a particular atom will change, given a sufficient number of atoms, the rate of their decay is found to be constant.
In terms of the numbers of atoms present, it is as if apples changed spontaneously into oranges at a fixed and known rate.
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The age calculated is only as good as the existing knowledge of the decay rate and is valid only if this rate is constant over the time that elapsed.
Fortunately for geochronology the study of radioactivity has been the subject of extensive theoretical and laboratory investigation by physicists for almost a century.